RESEARCH PAPER
Concentration and risk assessment of metals in snow cover monitoring in urban and rural areas
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1
Faculty of Environmental Engineering, Lublin University of Technology, Lublin, Poland
2
Faculty of Mathematics and Information Technology, Lublin University of Technology, Lublin, Poland
3
Institute of Rural Health, Lublin, Poland
4
Department Fauna and Systematics of Invertebrates, National Academy of Sciences, Ukraine, Kyiv, Ukraine
Corresponding author
Justyna Kujawska
Faculty of Environmental Engineering, Lublin University of Technology, Nadbystrzycka 40B, 20-618, Lublin, Poland
Ann Agric Environ Med. 2024;31(2):205-211
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ABSTRACT
Introduction and objective:
Snow cover serves as a unique indicator of environmental pollution in both urban and rural areas. As a seasonal cover, it accumulates various pollutants emitted into the atmosphere, thus providing insight into air pollution types and the relative contributions of different pollution sources. The aim of the study is to analyze the distribution of trace elements in snow cover to assess the anthropogenic influence on pollution levels, and better understand ecological threats.
Material and methods:
The study was conducted in rural areas around the village of Wólka in the Lublin Province of eastern Poland, and in urban districts of the city of Lublin, capital of the Province. Samples were analyzed using Inductively Coupled Plasma-Mass Spectrometry, the Enrichment Factor (EF), and ecological risk indices (RI), were calculated to evaluate the contamination and potential ecological risks posed by the metals.
Results:
The findings indicate higher concentrations of metals like sodium and iron in urban areas, likely due to road salt use and industrial activity, respectively. Enrichment factors showed significant anthropogenic contributions, particularly for metals like sodium, zinc, and cadmium, which had EF values substantially above natural levels. The potential ecological risk assessment highlighted a considerable ecological threat in urban areas compared to rural settings, primarily due to higher concentrations of metals.
Conclusions:
The variation in metal concentrations between urban and rural snow covers reflects the impact of human activities on local environments. Urban areas showed higher pollution levels, suggesting the need for targeted pollution control policies to mitigate the adverse ecological impacts. This study underscores the importance of continuous monitoring and comprehensive risk assessments to effectively manage environmental pollution.
ACKNOWLEDGEMENTS
The study was funded by research grants from the Polish Ministry of Education and Science in Warsaw, Poland. (Grant Nos. FD-20/IS-6/999, FD-20/IS-6/019, FD-20/ IS-6/021, FD-20/IS-6/050).
REFERENCES (25)
1.
Onuchin A, Kofman G, Zubareva O, Danilova I. Using an urban snow cover composition-based cluster analysis to zone Krasnoyarsk town (Russia) by pollution level. Polish J Environ Stud. 2020;29:4257–4267. doi:10.15244/pjoes/118168.
2.
Szwed M, Kozłowski R. Snow cover as an indicator of dust pollution in the area of exploitation of rock materials in the Świętokrzyskie Mountains. Atmosphere (Basel). 2022;13. doi:10.3390/atmos13030409.
3.
Nawrot AP, Migała K, Luks B, Pakszys P, Głowacki P. Chemistry of snow cover and acidic snowfall during a season with a high level of air pollution on the Hans Glacier, Spitsbergen. Polar Sci. 2016;10:249–261. doi:10.1016/j.polar.2016.06.003.
4.
Dinu M, Moiseenko T, Baranov D. Snowpack as indicators of atmospheric pollution: The Valday Upland. Atmosphere (Basel). 2020;11. doi:10.3390/ATMOS11050462.
5.
Pizarro J, Vergara PM, Cerda S, et al. Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes. Sci Rep. 2021;11:1–10. doi:10.1038/s41598-021-93895-1.
6.
He M, Yan P, Yu H, et al. Spatiotemporal modeling of soil heavy metals and early warnings from scenarios-based prediction. Chemosphere. 2020;255:126908. doi:10.1016/j.chemosphere.2020.126908.
7.
Yuan D, Liu Y, Guo X, Liu J. Characteristic contaminants in snowpack and snowmelt surface runoff from different functional areas in Beijing, China. Environ Sci Pollut Res. 2018;25:36256–36266. doi:10.1007/s11356-018-3501-1.
8.
Siudek P, Frankowski M, Siepak J. Trace element distribution in the snow cover from an urban area in central Poland. Environ Monit Assess. 2015;187:1–15. doi:10.1007/s10661-015-4446-1.
9.
Bełcik M, Grzegorzek M, Canales FA, Struk-Sokołowska J, Kaźmierczak B. Examination of interactions between heavy metals and benzotriazoles in rainwater runoff and snowmelt in an urban catchment in Poland. Water Resour Ind. 2024;31. doi:10.1016/j.wri.2023.100236.
10.
Mitra S, Chakraborty AJ, Tareq AM, et al. Impact of heavy metals on the environment and human health: Novel therapeutic insights to counter the toxicity. J King Saud Univ Sci. 2022;34:101865. doi:10.1016/j.jksus.2022.101865.
11.
Müller A, Österlund H, Marsalek J, Viklander M. The pollution conveyed by urban runoff: A review of sources. Sci Total Environ. 2020;709:136125. doi:10.1016/j.scitotenv.2019.136125.
12.
Nsenga Kumwimba M, Zhu B, Stefanakis AI, et al. Advances in ecotechnological methods for diffuse nutrient pollution control: Wicked issues in agricultural and urban watersheds. Front Environ Sci. 2023;11:1–37. doi:10.3389/fenvs.2023.1199923.
13.
Wallington TJ, Anderson JE, Dolan RH, Winkler SL. Vehicle emissions and urban air quality: 60 years of progress. Atmosphere (Basel). 2022;13. doi:10.3390/atmos13050650.
15.
International Organization for Standardization. PN-EN 15935:2022-01 Sludge, treated biowaste, soil and waste — Determination of loss on ignition.
16.
Looi LJ, Aris AZ, Yusoff FM, Isa NM, Haris H. Application of enrichment factor, geoaccumulation index, and ecological risk index in assessing the elemental pollution status of surface sediments. Environ Geochem Health. 2019;41:27–42. doi:10.1007/s10653-018-0149-1.
17.
Regulation of the Minister of the Environment of 23 July 2008. Journal of Laws of 2008, No. 143, item 896.
18.
Kim JE, Han YJ, Kim PR, Holsen TM. Factors influencing atmospheric wet deposition of trace elements in rural Korea. Atmos Res. 2012;116:185–194. doi:10.1016/j.atmosres.2012.04.013.
19.
Dong Z, Kang S, Qin X, et al. New insights into trace elements deposition in the snow packs at remote alpine glaciers in the northern Tibetan Plateau, China. Sci Total Environ. 2015;529:101–113. doi:10.1016/j.scitotenv.2015.05.065.
20.
Kamani H, Hoseini M, Safari GH, Jaafari J, Mahvi AH. Study of trace elements in wet atmospheric precipitation in Tehran, Iran. Environ Monit Assess. 2014;186:5059–5067. doi:10.1007/s10661-014-3759-9.
21.
Li T, Wang Y, Li WJ, et al. Concentrations and solubility of trace elements in fine particles at a mountain site, southern China: Regional sources and cloud processing. Atmos Chem Phys. 2015;15:8987–9002. doi:10.5194/acp-15-8987-2015.
22.
Jarzyna K, Kozłowski R, Szwed M. Chemical properties of snow cover as an impact. 2017:1591–1607.
23.
Szwed M, Kozłowski R, Sliwa Z, Zeliaś A, Przybylska J, Ludew M. Hidden in snow: Selected aspects of chemical composition of an urban snow cover (Kielce, SE Poland). Ochr Sr i Zasobow Nat. 2023;34:1–10. doi:10.2478/oszn-2023-0004.
24.
Grebenshchikova VI, Efimova NV, Doroshkov AA. Chemical composition of snow and soil in Svirsk city (Irkutsk Region, Pribaikal’e). Environ Earth Sci. 2017;76:1–10. doi:10.1007/s12665-017-7056-0.
25.
Moskovchenko D, Pozhitkov R, Zakharchenko A, Tigeev A. Concentrations of major and trace elements within the snowpack of Tyumen, Russia. Minerals. 2021;11. doi:10.3390/min11070709.